Citric Acid Esters of Monoglycerides (CITREM)

Citric Acid Esters of Monoglycerides (CITREM) a multifunctional emulsifier known for its stabilizing and dispersing capabilities, especially in fat-based and aqueous systems.

Description

What Is CITREM?

  • Chemical identity: Esters formed by reacting citric acid with mono- and diglycerides of edible fatty acids.
  • Appearance: Pale yellow to brownish waxy solid or viscous liquid.
  • HLB range: ~7–9, making it suitable for oil-in-water (O/W) emulsions.

Key Benefits

  • Emulsification: Stabilizes O/W emulsions, especially in high-fat or acidic systems.
  • Synergistic antioxidant: Chelates metal ions, enhancing oxidative stability of fats and oils.
  • Improved dispersion: Helps disperse fine particles and active ingredients uniformly.
  • Anti-spattering: Reduces oil spatter in frying applications.
  • Fat bloom control: Useful in chocolate and confectionery to stabilize fat crystals.

Functional Roles

Function Description
Emulsifier Maintains stable O/W emulsions in food, cosmetics, and pharma
Antioxidant synergist Chelates metals to prevent oxidation in fat-rich systems
Dispersant Enhances uniform distribution of solids and actives
Anti-spatter agent Reduces oil splatter during frying
Crystal modifie Controls fat bloom and crystallization in chocolate

 

Applications by Industry

  • Food:
    • Chocolate, margarine, sauces: Improves stability, prevents bloom, reduces spattering
    • Bakery and dairy: Enhances emulsion stability and texture
  • Pharmaceuticals:
    • Used in lipid-based drug delivery systems and emulsions
  • Cosmetics:
    • Creams, lotions, sunscreens for emulsion stability and antioxidant support
  • Industrial:
  • Metalworking fluids and lubricants for dispersing and anti-corrosion properties

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